If the offers provided by buses do not suit your needs, trains and carpooling could represent a good alternative for this distance.
What time do the busses to Munich leave?
The average duration of the journey is 9 hours and 39 minutes, but the fastest bus connections get you to Munich in 8 hours and 30 minutes. The first bus is scheduled at 00:07 and the last one at 22:07.
By bus from Florence to Munich: which companies offer the service?
There are many companies cooperating with virail, among which also FlixBus with buses to Munich.
Flixbus is undoubtedly one of the youngest and most famous bus companies in whole Europe. With more than 40 millions passengers only in 2017, Flixbus offers national and international bus connections, also with night buses.