If there are changes in your route, make sure you always have enough time to walk from one platform to the other and never forget the possibility of delay that could make you miss the second train.
Since the journey between Odesa and Kyiv is relatively short, you can consider carpooling or bus as alternative ways of transport with cheapest prices and similar duration.
In which stations can you take the train to Kyiv and where will you arrive?
The trains to Kyiv will leave from Odesa-Holovna and will arrive at Kyiv-Pasazhyrsky.
When are the first and last trains from Odesa to Kyiv scheduled?
The average duration of the journey is 10 hours and 32 minutes, but the fastest connections take you to Kyiv in 7 hours and 1 minute. The first train leaves from Odesa at 05:09, while the last one leaves at 22:09.